(E)-2-[(2,4-Dichlorophenyl)iminomethyl]-6-methylphenol
نویسندگان
چکیده
The title compound, C(14)H(11)Cl(2)NO, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. There are two mol-ecules in the asymmetric unit. Head-to-tail π-π inter-actions [centroid-to-centroid distances of 3.682 (2), 3.708 (2), 3.904 (2) and 3.910 (2) Å] between adjacent mol-ecules produce two symmetry-independent infinite chains running along the b axis.
منابع مشابه
2-[(2,4-Dimethylphenyl)iminomethyl]-6-methylphenol
The title compound, C(16)H(17)NO, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The mol-ecule is almost planar, with a dihedral angle of 4.61 (4)° between the aromatic rings. The molecular structure is stabilized by an intramolecular O-H⋯N hydrogen bond which generates a six membered ring.
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In the title compound, C(37)H(30)Cl(4)N(2)O(2), the pyridinone ring adopts a twisted half-chair conformation. In the octa-hydro-indolizine fused-ring system, the piperidine ring is in a chair conformation and the pyrrole ring is twisted about the C-N bond linking the five- and six-membered rings. The mol-ecular structure features an intra-molecular C-H⋯O inter-action and the crystal packing is ...
متن کامل2-(2,4-Dichlorophenyl)-2-oxoethyl 4-methoxybenzoate
In the title compound, C(16)H(12)Cl(2)O(4), the dihedral angle between the benzene rings is 70.11 (6)°. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds into a three-dimensional network. A C-H⋯π inter-action is also observed.
متن کامل3-(2,4-Dichlorophenyl)-5-methyl-1,2,4-oxadiazole
In the title compound, C(9)H(6)Cl(2)N(2)O, the dihedral angle between the oxadiazole and benzene rings is 1.7 (2)°. In the crystal, the mol-ecules are linked into chains along the b axis by short inter-molecular Cl⋯O contacts [3.019 (3) Å].
متن کامل2-(2,4-Dichlorophenyl)acetic acid
In the title compound, C(8)H(6)Cl(2)O(2), the dihedral angle between the C-C(=O)-OH carboxyl unit and the benzene ring is 70.70 (4)°. In the crystal, mol-ecules are linked into inversion dimers by pairs of O-H⋯O hydrogen bonds. The dimers are linked into chains extending along [001] by weak C-H⋯Cl inter-actions.
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009